In an earlier post, I discussed the concept of energy density and showed the values of energy density for a variety of fuels. The big take-away message of that post was that there is a whole lot of energy stored in a gallon of gasoline! Gasoline, diesel, etcetera are high-energy-density fuels and that is very convenient for automobile and airplane applications. You can pack the energy to travel a long way into a relatively small and light package.
How do batteries compare? Before we dive into the specifics of it, the short answer is: batteries have much, much lower energy densities than liquid fuels. That’s probably not a big surprise to a lot of folks, because, well, if they did have high energy density, our electric cars would be able to travel 300 miles between recharges, and we’re well aware that they can’t do that yet.
There are a number of subtleties to considering battery energy density. A major one is that the amount of energy a given battery can deliver varies depending on how quickly you are drawing on the battery. Generally speaking, the faster you draw on the battery, the less total energy you will get out of the battery. Batteries are normally specified using the 20-hour discharge rate, that is, a 100 amp-hour battery could be expected to deliver 5 amperes at the battery voltage for 20 hours. Another major consideration is a battery’s depth of discharge. The gas tank of a car, to use an analogy, can be filled to 100% full and driven down to 0% full, i.e. empty, with no damage to the car. A battery, on the other hand, has a maximum depth of discharge it can tolerate before suffering damage. This isn’t a concern for disposable batteries, of course, but for rechargeables it’s something to be aware of. This comes up a lot in designing electric storage for renewable energy sytems, which usually use lead-acid batteries. Systems will be designed for something like routine discharge to 50% full, with perhaps occasional discharge to 20% full.
Let’s look in more detail at some different types of batteries… and believe me, there are a lot of different types! I think I’ll just list the common battery technologies and what they’re used for, and then present a comparison table.
Alkaline batteries. These are the very common AA, AAA, D, and C cells that we use for flashlights, radio, and so on. Energy density is not bad, for a battery, but these batteries are not really rechargeable, they are one-use and get rid of them; referred to as “disposable” or “primary” batteries.
Carbon Zinc batteries. Also disposable (one-use) batteries, these are cheap but poor-performing batteries. Available in common sizes like AA, AAA, D, C, these are sometimes called dry cells. They’re advertised as “heavy duty” or “super duty” batteries. They were much more common a few decades ago, now people mostly use alkaline cells.
NiCad batteries. I think of Nickel Cadmium batteries as “my father’s rechargeable batteries.” More expensive than alkalines to purchase, but rechargeable many times. I've never had good success managing against the “memory effect” they have, and their output voltage is lower than alkalines, so I found them to be short-lived in devices. I won't buy them anymore, and instead I buy...
NiMH batteries. Nickel Metal Hydride batteries are newer-technology rechargeables. These are pretty good! Used in humble forms like AA and AAA batteries all the way up to electric and hybrid vehicles.
Lithium Ion batteries. Another rechargeable technology, these are often used for portable electronics applications—laptops, camcorders, and so on. Good energy density for a rechargeable battery.
Lead-Acid batteries. This is the type of battery you have in your car. A very well established technology, it is cheap on a per-watt-hour-delivered basis, and is rechargeable. This is generally the technology of choice for electricity storage for a solar array or other renewable energy source. The typical lead-acid battery requires some care and maintenance in its use: it contains sulfuric acid which can be spilled, it generates flammable hydrogen gas when being charged, and you need to be careful not to freeze it (and its freezing temperature changes as a function of its state of charge!). Variations of the basic technology exist to eliminate or reduce some of these drawbacks, by sealing in or immobilizing the electrolyte—these are sealed gel-cell or absorbed glass mat (AGM) batteries, and are more expensive than the garden-variety lead-acid battery. Also, lead-acid batteries are engineered to optimize certain characteristics at the expense of others—car batteries, for example, are engineered to be able to deliver a lot of current for a short time, but can only be drawn down a little bit (say 20%) before causing damage to the battery; in contrast, deep-cycle batteries for storage for a solar array are meant to be repeatedly discharged deeply (80% discharged) and recharged, but can’t provide as much current in a short time as an automotive battery.
Alright, we’ve discussed different battery types. Let’s take a look at a table comparing these battery types with each other and with gasoline as a representative of liquid fuels. The table shows the energy density on a mass and volume basis, as well as values normalized to that of gasoline, much like I did in the earlier posting on energy density. I’ve also added a column listing how much weight of batteries, or volume of batteries, you’d need to equal the energy content of 15 gallons of gasoline, about the capacity of a typical car’s gas tank. Note that the battery types listed in italics are disposable one-use battery types; the rest are rechargeable.
So, what do we learn from the table? Well, first off, all types of batteries are chumps compared to gasoline in terms of energy density. There's just no way around that. By looking at the last two columns, you can see that it would take a preposterous volume and weight of any type of battery to give you the same energy held in one 15-gallon tank of gasoline. And, in fact, batteries in electric and hybrid vehicles do spend a lot of their space and weight on battery packs, and they don't have great range (on electricity). Partly, that's something we just have to live with. But, the story isn't quite as simple as that, of course. One thing working in favor of batteries in vehicles is the system's efficiency. By that, I mean that energy drawn from the battery to power a car really does mostly go to moving the car, as these electric motors are quite efficient (80%+). In contrast, internal combustion engines only convert something like 20% or 25% of gasoline's chemical energy to motive force. (Thermodynamics...it's not just a good idea...it's the LAW!)
Looking at the individual battery types, it's pretty clear that Li-ion and NiMH are the winners in that they have the best energy densities for rechargeable batteries. Only alkaline technology gives comparable performance, and since it's a one-time use battery it's clearly unsuitable for something like an electric car.
I got a lot of the values in the table from this source: http://www.allaboutbatteries.com/Battery-Energy.html
I hope this has been interesting!
